Functional Groups
Organic Reactions
Solubility
pH
Thermochemical Principles
100

-OH functional group attached a carbon with two alkyl groups on either side

Secondary alcohol


100

Type of reaction from alkane to haloalkane

Substitution

100

Symbol for solubility product

Ks

100

[H3O+] = _______

10-pH

100

Energy required to remove one mole of electrons from the outer shell of one mole of gaseous atom

First ionisation energy

200

-NHfunctional group

Amine

200

Type of reaction from primary alcohol to aldehyde to carboxylic acid

Oxidation

200

MgCl2 type solid

AB2

200

pH + pOH = ____

14

200

Atomic radii _______ across a period and _______ down a group

Decreases, increases

300

R-X functional group

Haloalkane

300

Reagent needed reduce ketone to secondary alcohol

NaBH(in basic conditions)

300

ABand A2B calculation of Ks

Ks = 4s3

300

pKa = _______

-log Ka

300

Weak intermolecular forces between ALL molecules

van der Waal's forces (or temporary dipole-dipole forces)

400

R-COCl functional group

Acyl chloride

400

Reagent AND conditions required to perform addition conversion from alkene to alkane

Heat with H2, Ni or Pt catalyst

400

If Qs < Ks, ppt will....

Not form


400

Ka expression

Ka = [A-] [H3O+] / [HA]

400

The enthalpy change when one mole of substance is formed from its individual elements in standard conditions

Standard enthalpy of formation

500

R-CHO functional group

Aldehyde

500

Name of process where triglyceride (fat/oil) is converted to sodium salts of fatty acids + propan-1,2,3-ol

Saponification (or hydrolysis under alkaline conditions)

500

Solubility of one salt is reduced by adding an ion that is already present in solution

Common ion effect

500

Region on titration curve where acid/base conjugate pair are in roughly equal concentrations

Buffer zone


500

The sublimation of NH4NOfrom solid to gas is an ENDOTHERMIC reaction. Therefore the entropy of the system _______ and the entropy of the surroundings _________.

Increases, decreases

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