What are some examples of network covalent bonds?
Diamond, Graphite, etc.
You dissolve 3.0 mol of glucose in 2.0 kg of water.
What is the molality?
m = mol solute / kg solvent
m = 3.0 / 2.0
m = 1.5 m
What is the process of solid turning into gas?
Sublimation
Semiconductors: conduct electricity
Insultators: blocks flow of electrical current (no doping)
How are intermolecular forces and vapor pressure related?
Inverse
What are metallic solids?
A type of network covalent solid
A substance has ∆Htrans = 10.0 kJ / mol and ∆Strans = 20.0 J / mol
What is the transition temperature?
Ttrans = ∆Htrans / ∆Strans
10 kJ => 10,000 J
T= 10,000 / 20
T = 500 K
What is viscosity?
resistance of a liquid to a flow
What are superconductors?
What is deposition?
Gas => solid
What are molecular solids?
Covalently bonded with long range order (type of crystalline solids)
How much heat is required to heat 2.0 mol of a substance with a molar heat capacity of 10 J/(mol·K) from 20°C to 30°C?
q = nCm∆T
n = 2.0 mol
∆T = 30 - 20 = 10 degrees C
q = (2.0) (10) (10)
q = 200 J
What type of slope does the liquid phase diagram have?
Negative
What is critical temperature?
Highest temperature at which a substance can still exist as a liquid
What is the opposite of vaporization?
Condensation
Copper crystallizes in a face-centered cubic (FCC) lattice structure. Calculate the net number of atoms that belong strictly to one FCC unit cell.
4 atoms per unit cell
1. (8*1/8) = 1 + (6*1/2) = 3
2. 1 + 3 = 4
Calculate ΔG:
ΔH=20 kJ
T=300 K
ΔS = 0.050 kJ / K
ΔG = ΔH - TΔS
= 20 - (300)(0.050)
ΔG = 5 kJ
Describe the difference between melting point and boiling point
Melting point - solid => gas
Boiling point - liquid => gas
What is the relationship between conductivity and temperature?
What is the difference between molarity and molality?
M = mol / L
m = mol / kg
Polonium crystallizes in a Simple Cubic (primitive) lattice structure. Calculate the net number of atoms belonging strictly to one simple cubic unit cell.
A solution has Kf = 2.0 degrees C / m
and m = 0.50 m
What is the freezing point charge?
ΔTfus = -Kfmi
ΔT = -(2.0)(0.50)(1)
= -1.0 degrees C
What is the difference between enthalpy and entropy?
Enthalpy (total heat)
Entropy (randomness)
What are the two types of doping?
P- type : positive holes (spaces without electrons) added to semiconductor
N- type: negative electrons added to semiconductor
Supersaturated: more solute than can be dissolved
Saturated: max of amount of solute dissolved