Chemistry 1
Unit 1: Reactions in Aqueous Solutions
Unit 2: Gases
Unit 3: Thermochemistry
Unit 4: Kinetics
100

3115P3-

This atom has _ neutrons.

This atom has _ protons.

This atom has _ electrons.

1) What is 16

2) What is 15

3) What is 18

100

This term means that the molecule can conduct electricity when dissolved in water.

What is Electrolyte?

100

1 atm = _ torr

What is 760?

100

A system does 975 J of work on its surroundings while at the same time it absorbs 625 J of heat. What is the change in internal energy, ΔU, for the system?

-350 J

100

What is the reaction order of the following rate law?

Rate = k[NO2][Na]

Second order

200

This type of electromagnetic wave has the longest wavelength.

What are radio waves?

200

List the halogens from lowest to highest activity(Activity series).

I < Br < Cl < F

200

What is the Ideal Gas Law and what does each term represent.

PV = nRT

Pressure, Volume, # of moles, Gas constant, Temperature

200

1 cal = __ J

What is 4.184?

200

What is the rate law of the following:

__________________________________________

[F2](M) | [ClO2](M) | Initial Rate(m/s) |

-----------------------------------------------------------

   0.1    |     0.01    |      1.2*10-3        |

   0.1    |     0.02    |      4.8*10-3        |

   0.2    |     0.01    |      1.2*10-3        |

Rate = k[ClO2]2

300

This element is 1s22s22p63s23p63d44s2.

What is Chromium?

300

Assign oxidation states for the following reaction and determine what the oxidizing and reducing agents are.

Zn(s) + CuSO4(aq) __> ZnSO4(aq) + Cu(s)

Zn(s) + CuSO4(aq) __> ZnSO4(aq) + Cu(s)

 0     +2 +6 -2       +2 +6 -2          0


CuSO4(aq) is oxidizing agent

Zn(s) is reducing agent

300

In these conditions, gases behave ideally.

What is high temperature and low pressure?

300

For calorimetry problems, this temperature unit is used.

What is Celsius?

300

If the energy of the reactants is 120 kJ, the energy of the products is 180 kJ, and the climax of the equation is 240 kJ, what is the activation energy and what is the ∆H of the equation?

E= 120 kJ

∆H = 60 kJ

400

This element has the highest electronegativity.

What is Fluorine?

400

Categorize the following molecules into strong or weak acids or bases.

HCl, HBr, HClO4, H3PO4, HF, Ca(OH)2, NaOH

Strong acids: HCl, HBr, HClO4

Weak acids: H3PO4, HF

Strong bases: Ca(OH)2, NaOH

Weak bases: None

400

An open manometer is filled with mercury and the closed end is filled with ammonia. If the mercury rises 23.4 mm on the side of the manometer attached to the ammonia, what is the pressure of the ammonia if the atmospheric pressure is 716 torr?

693 mmHg

400

Calculate the standard heat of formation, ΔH°f, for CH4

CH4(g) + 4F2(g) → CF4(g) + 4HF(g)    ΔH°rxn = -1942 kJ/mol

C(graphite) + 2F2(g) → CF4(g)    ΔH°rxn = -933 kJ/mol     

H2(g) + F2(g) → 2HF(g)    ΔH°rxn = -542 kJ/mol

-75 kJ/mol

400

What would the units be for the rate constant of a fourth-order reaction (time unit is arbitrary)?

1/(M3)(arbitrary time unit)

500

1) List the IMFs from weakest to strongest.

2) These IMFs are present in NH3

1) London Dispersion Forces, Dipole-Dipole, Hydrogen Bonding

2) All 3

500

Solve this half-reaction problem in a basic solution.

CrO42-(aq) + AsH3(g) __> Cr(OH)3(s) + As(s)

AsH3(g) __> As(s) + 3H+ + 3e- (Since As proportions are equal, we balance the hydrogen amount and charges for this half)

CrO42-(aq) + 5H+ + 3e- __> Cr(OH)3(s) + H2O(l)

(Cr proportions are equal so balance hydrogen, oxygen, and charges)

CrO42-(aq) + AsH3(g) + H2O(l) __> Cr(OH)3(s) + As(s) + 2OH- (Combine equations, cancel like terms, replace H+ ions with OH- because it's in a basic solution)

500

This is the average particle speed (m/s) of CO2 at 27.0oC using root mean square.

What is 412 m/s?

500

A 0.1111 g sample of octane, C8H18, was burned in the presence of excess O2 in a bomb calorimeter. The heat capacity of the bomb calorimeter was 1.726 x 103 J/℃. The temperature of the calorimeter and the 1.200 x 103 g of water rose from 21.11℃ to 23.05℃. What is the heat combustion per gram of octane?

-118 kJ/g

500

Using steady-state equilibrium, find the rate law of the second step.

Step 1    NO2(g) + NO2(g) ⇌ NO3(g) + NO(g)

Step 2    NO3(g) + CO(g) → NO2(g) + CO2(g)

Rate = k[NO2]2[CO]/[NO]

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