fischer projections
cyclic carbs
redox
glycosidic bond
polysaccharides
100

describe how to name carbohydrates with this 

-aldehyde: name by aldo(# of carbon)+ose

100

what are cyclic carbohydrates called

haworth structures

100

Oxidation is...

increasing C-O bonds, decreasing C-H bonds

100

what is the most common glycosidic bond

1,4


100

Which of the following is only found in plants,

cellulose, starch, and glycogen

cellulose

200

how do you name a carbohydrate with this functional group

ketone: name by keto(# of carbon)+ose

200

from what carbon do you start counting


start counting counterclockwise from the O in the ring

200

Reduction is

decreasing C-O bonds, increasing C-H bonds

200

what makes a glycosidic bond alpha

the original left monosaccharide was alpha (O will come down off of the first carbon )


200

why can't humans digest cellulose

humans cannot break the beta 1,4  glycosidic linkages (humans can’t gain nutritional value from it)

300

How many chiral carbons are in this structure


4

300

a monosaccharide will have ___ ring(s)

a disaccharide will have ___ ring(s)

a polysaccharide will have ___ ring(s)

1,2,2+

300

oxidation  of an aldehyde will result in

carboxylic acid

300

what makes a glycosidic bond beta

the original left monosaccharide was beta (O will come up off of the first carbon )


300

if starch is made by plants, why can humans digest it?

it has alpha 1,4 glycosidic linkages

400

What does it mean if a fischer projection is L

OH on the left for the 1st chiral carbon from the bottom

400

What does it mean if a haworth structure is alpha

OH is on bottom of carbon 1

400

reduction of aldehyde

results in primary alcohol


400

what process forms a glycosidic bond


dehydration synthesis(pull out water)

400

how do we store polysaccharides and what type of glycosidic bonds are they

glycogen, 1,4 alpha glycosidic bonds

500

What does it mean if a fishcer projection is D

OH on the right for the 1st chiral carbon from the bottom


500

What does it mean if a haworth structure is beta

Is OH is on top for Carbon 1


500

what will happen during the oxidation AND reduction of a ketone

Oxidation: nothing (already at max C-O bonds) 

reduction: secondary alcohol

500

hydrolysis of a disaccharide will break the ____ and form 2 ______

1,4 glycosidic bond

monosaccharides

500

give me the 2 examples of starch that vonderheide gave us and describe the difference

→amylose is what makes up starch, alpha 1,4 glycosidic bonds (long chain)

→amylopectin, same thing but more branched, still with alpha 1,4 glycosidic 

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