Heat Transfer
Calorimetry
Hess's Law
100

Classify the following as either endothermic or exothermic and give the sign of qsys: 

a. Water evaporating

b. A person shivering

c.  Freezing water 

d. Cooking an egg


a. endothermic

b. exothermic

c. exothermic

d. endothermic

100

When 175 mL of water at 25C is mixed with 55 mL of water at 96C, what is the final temperature
of the mixture? 

Assume qsoln = –379 J 

What is 95.6C?

100

Calculate ΔH for the process

Hg2Cl2(s)⟶2Hg(l)+Cl2(g)

from the following information:

Hg(l)+Cl2(g)⟶HgCl2(s) ΔH=−224kJ Hg(l)+HgCl2(s)⟶Hg2Cl2(s)ΔH=−41.2kJ


265 kJ


200

The change in internal energy of the
system, Usys: 

A system absorbs 55 kJ of heat and does 45 kJ of work

What is 10 kJ?

200

You have 12.0 grams of calcium chloride to 115 grams of water, and the solution temperature
increases from 29.2 °C to 35.0 °C. 

Find  the  heat  gained  or  lost  by  the
reaction, qrxn, in J.  Assume that the solution has a specific heat of 4.18 J/g·°C.

What is 25.78 kJ/mol?

200

4NH3(g)+5O2(g)⟶4NO(g)+6H2O(l) ΔH=−907kJ 

2NO(g)+O2(g)⟶2NO2(g) ΔH=−113kJ 

3NO2+H2O(l)⟶2HNO2(aq)+NO(g) ΔH=−139kJ 

Determine the total energy change for the production of one mole of aqueous nitric acid by this process.

495 kJ/mol


300

Find q when 25.0 g of water is heated from 22.0C to 100.0C.

What is 8151 J?

300

Calculate the enthalpy change for the decomposition of the following reaction:

COH2 +O2 = H2O + CO2 

C-H: H= 414 kJ/mol 

O-H: H= 464 kJ/mol

C=O: H=799 kJ/mol 

What is -899 kJ/mol ?


300

Calculate the standard enthalpy of formation of n-butane, given that the standard enthalpies of combustion of n-butane, C(graphite) and H2(g) are –2878.5 kJ mol–1, –393.5 kJ mol–1 and –285.8 kJ mol–1 respectively.

What is -124.5 kJ/mol?

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