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100

a region of space in which there is a high probability of finding an electron

atomic orbital

100


molecular structure


arrangement of atoms in a molecule or ion

100

bond distance


distance between the nuclei of two bonded atoms

100


2.998 x 10^8 m/s

The speed of light (C)

100

ionic bond

strong electrostatic force of attraction between cations and anions in an ionic compound

100

This is an example of one.

Lewis structure

100

Amplitude



Height of a wave

100

s orbital


spherical region of space with high electron density

100

inert pair effect


the tendency of heavy atoms to form ions in which their valence s electrons are not lost

100

electron configuration


the arrangement of electrons in an atom

100

electron-pair geometry


arrangement around a central atom of all regions of electron density

100


a particle of light

Photon

100

vector


quantity having magnitude and direction

200

spin quantum number


direction of the intrinsic quantum"spinning" of the electron

200

two or more Lewis structures that have the same arrangement of atoms but different arrangements of electrons

resonance forms

200

polar molecule




molecule with an overall dipole moment

200


1nm = 10^-9m

Nanometer (nm)

200

lone pair


a pair of electrons that is not involved in bonding and that belongs exclusively to one atom

200

This is an example of this type of bond

Single bond

200


the shape of the orbital

angular momentum


200

shell


set of orbitals with the same principal quantum number

200

valence bond theory


description of bonding that involves atomic orbitals overlapping to form σ or π bonds, within which pairs of electrons are shared

200

valence electrons


electrons in the outermost or valence shell

200

dipole moment


property of a molecule that describes the separation of charge determined by the sum of the individual bond moments based on the molecular structure

200


idealized perfect absorber of all incident electromagnetic radiation

Blackbody

200


coexistence of orbitals from two different atoms sharing the same region of space, leading to the formation of a covalent bond

overlap

300

d orbital

region of space with high electron density that is either four lobed or contains a dumbbell and torus shape;

300

axial position


location in a trigonal bipyramidal geometry in which there is another atom at a 180° angle and the equatorial positions areat a 90° angle

300


arrangement around a central atom of all regions of electron density


electron-pair geometry

300


Energy = h x frequency

Planck's formula

300

triple bond

bond in which three pairs of electrons are shared between two atoms

300

These eight valence electrons show this.

Octet rule

300

magnetic quantum number



orientation of the orbital

300


set of orbitals in an atom with the same values of n and l

subshell

300

Hund's rule




every orbital in a subshell is singly occupied with one electron before any one orbital is doubly occupied

300

valence shell


the outermost shell of electrons in a ground-state atom

300

polar molecule


molecule with an overall dipole moment

300


a spectrum of separate and distinct colors in which not all colors are present



Discrete Spectrum

300

node


plane separating different lobes of orbitals, where the probability of finding an electron is zero

400


dumbbell-shaped region of space with high electron density


p orbital

400

   

         bond angle


angle between any two covalent bonds that share a common atom

400


shape in which two outside groups are placed on opposite sides of a central atom

linear

400

Frequency


Frequency

400


molecule that contains an odd number of electrons



free radical

400

This is what the pictorial representation would look like:

Orbital Diagraom

400

f orbital



multilobed region of space with high electron density

400


mathematical description of an atomic orbital that describes the shape of the orbital;

wavefunction

400

Pauli exclusion principle


specifies that no two electrons in an atom can have the same value for all four quantum numbers

400

resonance forms


two or more Lewis structures that have the same arrangement of atoms but different arrangements of electrons

400

tetrahedral


shape in which four outside groups are placed around a central atom such that a three-dimensional shape is generated with four corners and 109.5° angles between each pair and the central atom

400

symbolized by n, indicates the main energy level occupied by the electron

principle quantum number

400

pi bond

covalent bond formed by side-by-side overlap of atomic orbitals; the electron density is found on opposite sides of the internuclear axis

500

The link between the Carbon atoms is an example of this

Double Bond

500

bond dipole moment


separation of charge in a bond that depends on the difference in electronegativity and the bond distance represented bypartial charges or a vector

500

Octahedral


shape in which six outside groups are placed around a central atom such that a three-dimensional shape is generated with four groups forming a square and the other two forming the apex of two pyramids

500

formal charge


charge that would result on an atom by taking the number of valence electrons on the neutral atom and subtracting the nonbonding electrons and the number of bonds

500

molecule containing at least one main group element that has more than eight electrons in its valence shel

hypervalent molecule

500

The "E"s represent this

equatorial position

500


orbital created by combining atomic orbitals on a central atom

hybrid orbital

500

core electron


electron in an atom that occupies the orbitals of the inner shells

500


procedure in which the electron configuration of the elements is determined by "building" them in order of atomic numbers

Aufbau principle

500

resonance hybrid


average of the resonance forms shown by the individual Lewis structures

500

trigonal bipyramidal


shape in which five outside groups are placed around a central atom such that three form a flat triangle with 120° angles between each pair and the central atom, and the other two form the apex of two pyramids, one above and one below the triangular plane

500

 Used to find the black body radition to fit experimental observation

Planck constant 


6.626 x 10^-34 Js

500

valence bond theory

description of bonding that involves atomic orbitals overlapping to form σ or π bonds, within which pairs of electrons are shared

600

sigma bond

covalent bond formed by overlap of atomic orbitals along the internuclear axis

600

hybridization

model that describes the changes in the atomic orbitals of an atom when it forms a covalent compound

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