Titration
Thermodynamics
Solubility
pH
Wildcard
100

what is the pH at the half equivalence point of a HF titration. 

PKa for HF = 3.8

3.8

100

is entropy conserved like enthalpy, energy, and mass

no entropy can be created but not destroyed. It's not a form of energy like heat.

100

what is the Ksp equation for Ca(OH)2

Ksp=[Ca2+][OH-]2

100

what is the pH of a 10 molar solution of HCl

-log(10)=-1

100

does it matter if the McRib and exercise mats both share a certain chemical.

No many chemicals have many uses. these are likely the share many chemicals. cellulose for example is the primary chemicals of most plants fiber and is likely in both.

200

you are titrating 15mL of 0.5M solution of acetic acid with a 0.1 M solution of NaOH. How many mL need to be added in order to reach the equivalence point

15mL * 0.5M / 0.1m = 75mL

200

is a reaction has a delta H of -4kJ/mol is it endo- or exo- thermic.

exothermic. the chemical is looking 4kJ/mol to the environment.

200

In pure water AlPO4 has a Ksp of 9.84*10-21 what is it's solubility?

sqrt(9.84*10-21) = 9.92*10-11

200

what is the pH of a 1M solution of HF

HF pKa=3.8

Ka = 1.58*10-4​​​​

-log(sqrt(1.58*10-4 * 1M))


pH=1.9

200

Name a chemical,that isn't water, you'd commonly find in the body. (chemical not element, carbon doesn't work)

many answers:

glucose, lipids, GABA, Hemoglobin, protein

300

how many mols of sodium acetate would you add to 1 mol of acetic acid to make a 4.5 pH buffer.

pKa for acetic acid = 4.76

0.55 mols of sodium acetate

10(4.5-4.76)=0.55 mol

300

CaCO3(s) -> CaO(s) + CO2(g) 

DeltaH is positive
when is the reaction favored


at high tempratures

you can tell the entropy is positive bc it makes gas.

300

what concentration of SO42- is needed start precipitating BaSO4 from a 0.1M solution of Ba2+

BaSO4 Ksp=1.08*10-10

1.08*10-9M SO42-

Ksp=[SO42-][Ba2+]

300

if you have 1L of unbuffered 14 pH solution and you add 1 mol of HCl. what is the new pH? 

hint:use pOH

[OH-] = 1014-14 = 1M OH-

1M OH- - 1M H+ = 0M OH remaining.

pH = 7

300

What does Hydrofluoric acid do to you if you're exposed to it.

Skeletal fluorosis: makes bones brittle

400
you're titrating 15mL solution of 0.5M NH3​​​​ (acetic acid) with 0.1M NaOH. after 5mL what if your pH. 

pKa CH3COOH = 4.76


4.76 + log(0.1M*5mL / (15mL * 0.5M - 5ml * 0.1M)

=3.61

400

if one reaction has a delta G of 1kJ/mol and another has a delta G of 105 kJ/mol. do you know which one will react faster.

you cannot know. themodynamics is completely removed from reaction speed.

400

CdF2 Ksp = 6.44*10-3

CaF2 Ksp = 3.45*10-11

if F- is added to a solution of Cd2+ and Ca2+ which salt will first fall out of solution.


CaF2 the less soluble ion will be the first to fall out.

400

If you have a mixture of strong and weak acid. How do you calculate the pH. assume the weak acid is non negligable.

use the strong acid for the initial concentration of H+ when doing the ICE table for the weak acid.

400

what is the oxidation state of Mn in MnO4-

+7

-2*4 + +7 = -1

500

what is the pH at the equivalence point for 10mL 0.1M solution of NH3 being titrated with a 0.1M solution of HCl. 


PKa of NH4+ = 9.24

C = 0.1M*10mL/20mL

pH = -log(sqrt(Ka*C))

5.3

500

What is the Delta G for the reaction at 25C

H2 + 0.5O2 -> H2O

H2O Delta Hf = -285kJ/mol

H2O Sf = 69.95 J/mol*K


G = -285000 - 69.95 * (25+273)

= -305.8kJ/mol

500

the solubility of Al(OH)3 in a pH 10 solution is 3*10-22. What is the Ksp

Ksp=[OH]3[Al]

[OH] = 10pH-14

3*10-34

500

what is the pKa of an acid with a pH of 4 when 

[HA] = 2

[A-] = 5


4= pKa + log(5/2)

pKa = 3.6

500

What is Sebastian's favorite piece of glassware?

Soxhlet extractor. They're awesome.

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