Chemistry and Reactions
Catalysts
Catalyst & Fouling Management
Process Variables and Feed Effects
Refinery Fun Facts
100

This molecule contains a ring

What is an aromatic?

100
Traps particulates to prevent a rapid rise in pressure drop.

What is grading?

100

Coking and Metals

What are mechanisms to foul or deactivate catalyst?

100

Improves with higher H2 pressure

What is diesel cetane or jet smoke point?

100

Jamnagar Refinery

What is the world's largest refinery?

200

This reaction has the highest heat release per SCF (m3) of Hydrogen consumed.

What is olefin saturation?

200
3200 - 4300 ft2 or 300 - 400 m2 per gram

What is the surface area of catalyst?

200
Contaminant in feed from anti-foam injections

What is silicon?

200

Impacts diffusivity in and out of catalyst pores

What is viscosity?

200

Standard Oil of New Jersey (now ExxonMobil) started up the first commercial unit of this technology?

What is hydrotreating? (What is FCC is also okay)

300

If not removed, this molecule can deactivate reaction sites.

What is basic nitrogen?

300

2.5 Ratio

What is the maximize size difference between catalyst/grading layers?

300

May turn "soft" coke back into hydrocarbon.

What is catalyst hot stripping or hot H2 strip?
300

Feed Rate / Catalyst Volume

What is LHSV?

300

The technology was invented to process coal

What is hydrocracking?

400

A reaction that occurs as temperatures approach 850F or 450C

What is thermal cracking?

400

Increase surface area and optimize pore size

Improve metals dispersion

Increase metals contact

What is factors that increase catalyst activity?
400

Increase of 8x coking rate

What is the impact of cutting H2 partial pressure in half?

400

Increases make a significant difference in promoting the right reaction.

What is H2 partial pressure?

400

Most critical product from hydrocracking during WWII that resulted in more units being built

What is jet fuel?

500

Aromatic saturation and mercaptans 

What are reversible reactions?

500

Used in hydrocracking and dewaxing catalysts.

What is zeolite?

500

Is removed with high nickel content catalyst or grading.

What is arsenic?

500

Molecules on the verge of becoming coke

What is carbon residue?

500

200-300 bar

2900-4350 psi

The operating pressure of the original hydrocrackers in late 1920's.

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