Nomenclature
draw 2 of the following,
acetone, THF, DMSO, EtOH, MeOH, diethyl ether, DMF, acetic acid, dichloromethane
nicely done
Draw a reaction diagram for an SN1 reaction that is endothermic
two bumps, products higher than reactants in energy
Relationship between...
Diastereomers!
Drumroll please...
DBO = big bulky base,
heat and polar protic solvent push E2
draw 5-secbutyl-2,3,4-trichlorononane
nice
What does delta G stand for?
Gibbs free energy (how spontaneous the chemical reaction is)
find if + or - by doing Energy of "products" minus "reactants"
Draw a single meso compound
meso = compound with > or = 2 stereogenic centers but overall achiral
Ahora, dibujamos
C+ is @ a tertiary already, so no rearrangement, OH = BAD LG. protonates then Nu- attack
Which will have the highest bp?
a. 1-butanol
b. 1,4-butanediol
c. 2-butanol
d. 2-methyl-2-butanol
b. 1,4-butanediol
How many compounds are in the rate equation for an E1 reaction
1! just the compound with the LG, no base or Nu-
The definition of enantiomers
Compounds with the same atom connectivities, but are mirror images, and therefore not identical.
Picasso Time...
THF = Polar Aprotic which pushes SN2, strong Base, good Nu-, primary LG
name this guy
(1R,5R)-5-iodo-2-isopropylcyclohexanol
Alas, I shall draw
Keq is greater than 1
I will once again... be asking you to look at this drawing
Identical
Check this out...
Whenever doing Elimination on a ring with stereo chem., chair moment
Make up one and trade it with someone, see if they get it right, hehehe
Im going to hope it worked out
What does the Keq represent? And how can you calculate it?
Equilibrium constant, concentration of products over the concentration of reactants
opposite of delta G
alright... lemme draw this one
take a min, sit down
yeah... just give me a sec...
2 different products!
1 w/ just rearrangement
another w/ rearrangement then resonance!