The Greek letter Δ stands for ____________
"Change in"
In Gibbs Free Energy Calculations, temperature is expressed in ___________
Kelvin
What is the value of ΔG at 300 K for a reaction in which ΔH = –150 kJ/mol and ΔS= +2.00 kJ/mol·K?
ΔG= ΔH - TΔS
ΔG= -150 - (300 x 2) = -750
Phase State that has highest entropy
Gases
DH is +ve
Endothermic reaction
Calorimeter
The standard enthalpy of formation of an element is
zero
Compounds with a Highly negative enthalpy of formation
Very stable compound
Combustion reactions are always defined in terms of _____________
one mole of reactant
For the reaction A(g) + B(g) --> 2C(g) + D(g) + energy, what is the value of ΔS and ΔH?
ΔS is positive
ΔH is negative
What is the system, surroundings and universe in a flask of HCl
system: flask containing HCl
surroundings: everything else other than the flask
universe: system + surroundings
the products are at a higher energy level than the reactants
Endothermic reaction
Compounds with a Large positive enthalpy of formation
Unstable compound
A measure of the possible ways that the energy of a system can be distributed
Entropy
energy flowing from warm to cold
heat
DHvaporization of water is 40.7 what is the DHcondensation
DH cond= -40.7
Calculate energy absorbed by 8 g of copper when heated from 10C to 40C. specific heat =0.384J/(g.C)
q = cp x m x DT
q = 0.384 x 8 x 30
q = 92 J
Entropy increases when:
1. gases have more room to move
2. solid dissolves in a solution
3. total moles of gas products are more than moles of gas reactants
4. temperature increases
Study of heat changes that accompany chemical reactions and phase changes
thermochemistry
Energy absorbed in breaking bonds
Energy released in forming bonds
What is Endothermic?
What is Exothermic?
Use the information below to determine ΔH for the reaction represented by the equation .
the enthalpy of formation of the compounds and elements:
NO ΔHf= 90.25
O2 ΔHf= 0
NO2 ΔHf=33.18
ΔH = ΔHf (products) - ΔHf (reactants)
ΔH= (2x33.18) - [0 + (90.25 x 2)]
ΔH= 66.36 - 180.4 = -114.04
energy released or absorbed as heat when one mole of a compound is burned in oxygen
Enthalpy of combustion
Suppose that a chemical equation can be written as the sum of two other chemical equations. If two reactions have values of –658 kJ and +458 kJ, what is for the reaction that is their sum?
-658 + 458 = -200KJ
The total enthalpy of the products in a reaction is 0 kJ, and the total enthalpy of the reactants is 100 kJ. What is ΔH for the reaction?
0 - 100 = -100KJ
Use equations (a and b) to calculate ΔH for the following reaction (using Hess’s Law):
Hg2Cl2(s)⟶2Hg(l)+Cl2(g)
from the following information:
Equations a and b
HgCl2(s) ⟶ Hg(l)+Cl2(g) ΔH=224 kJ
Hg2Cl2(s) ⟶ Hg(l)+HgCl2(s) ΔH= 41.2 kJ
Add equations a and b and their ΔH
ΔH=224 kJ
ΔH= 41.2 kJ
224 + 41.2 = 265.2KJ