Properties
This is defined as the sum of thermodynamic system's internal energy and the product of its pressure and volume
What is Enthalpy
PV=nRT
What is Ideal Gas Law
This states that in any spontaneous process, the total entropy of an isolated system always increases, and heat cannot spontaneously flow from a colder body to a hotter body.
A dimensionless quantity that measures how much a real gas deviates from ideal gas behavior
What is Compressibility Factor
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What is Blaziken (my boi)
This is a thermodynamic property that measures the tendency of a substance to escape or vaporize from a phase, serving as a corrected pressure for real gases
What is Fugacity
F=C-P+2
What is Gibb's Phase Rule
This law relates partial pressures in an ideal gas mixture to the total pressure in vapor-phase systems.
What is Dalton's Law
A measure of the effective concentration of a species in a mixture.
What is Activity
This Chicago Cubs shortstop (baseball player), also known as Mr. Cub, hit 512 home runs throughout his career.
Who is Ernie Banks
This property is defined as the partial molar Gibbs free energy of a component in a mixture.
What is Chemical Potential
This equation of state introduces parameters “a” and “b” to account for intermolecular forces and finite molecular size.
What is Van der Waals equation
This states that all fluids, when compared at the same reduced temperature and reduced pressure, exhibit similar thermodynamic behavior
What is Law of Corresponding States
This condition occurs when a mixture boils at constant composition due to identical vapor and liquid compositions.
What is an Azeotrope
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What is Up
This property represents the difference between a real solution property and its ideal solution counterpart at the same T and P.
What is Excess Property
This modern equation of state
P = RT / (V - b) - a(T) / [V(V + b) + b(V - b)]
improves liquid density predictions and is widely used in industry.
What is the Peng-Robinson Equation
This law states that the rate of heat transfer is proportional to the temperature gradient.
What is Fourier's Law
This represents the maximum possible efficiency any heat engine can achieve.
What is a Carnot Engine
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What is "cool wind in my hair"
This is a thermodynamic potential that measures the useful work obtainable from a closed thermodynamic system at a constant temperature
What is Helmholtz Free Energy
(∂ S/∂ V)T = (∂ P/∂ T)V is an example of what
What is a Maxwell Relation
This states that in a system at equilibrium, the chemical potential of each component is equal across all phases present
What is Duhem's Theorem
This counterintuitive effect describes how some gases cool when expanded without doing work, but only below a certain temperature—and otherwise actually heat up.
What is the Joule–Thomson effect
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What is Deacon