Klingons
The first Klingon in Starfleet
Worf
Family owns a vineyard
Picard
What alien species did humans meet first?
Vulcan
Locutus
Best of Both Worlds, Parts I and II
Gorn
Arena
He had something to do with tribbles...
Koloth
He calls his best friend "old man"
Sisko
What is the Prime Directive?
First contact must not be initiated unless the species is warp capable so as to not disturb their natural development
"So... I lied. I cheated. I bribed men to cover the crimes of other men. I am an accessory to murder. But the most damning thing of all... I think I can live with it."
In the Pale Moonlight
Horta
Devil in the Dark
Enemy of Worf whose family are known Romulan collaborators
Duras
Has a dog named Porthos
Archer
Who made first contact with the Borg?
Captain Picard
or Archer on an extreme technicality
Tantalus Field
Mirror, Mirror
Jarada
The Big Goodbye
Quark's ex-wife
Grilka
Encountered the Caretaker
Janeway
Name the two Captains who have made first contact with the most species
Kirk and Janeway
Northwest Passage
"What if I made an appeal… to the Devil?"
Scorpion, Part I and II
Voth
Distant Origin
Kang's science officer
Mara
Has a nephew named Peter
Kirk
Name the first species/people group/organization we see Captain Kirk make first contact with
First Federation
Kamin
The Inner Light
Elaysian
Melora