Definitions
Relationships
Energy
Laws of Thermodynamics
Problems
100
Another name for thermal energy
What is heat
100
Relationship between q hot and q cold
What is q hot = -q cold
100
Unit of energy
What is Joules
100
First Law of Thermodynamics
What is the law that states that energy can not be created nor destroyed
100
Calculate the heat absorbed of a 175 g sample that starts at 23.45 degrees Celsius, raises to 26.85 degrees Celsius and has a specific heat of 4.284 G/gC
What is 2.49 x 10^3 J
200
A piece of equipment designed to measure for reactions at constant volume
What is bomb calorimeter
200
Equation for delta E for a reaction HINT: Bomb Calorimeter
q = heat capacity * [delta]T
200
Equation relating system and surrounding
What is [delta]E (system) = -[delta]E surrounding
200
What is an exothermic reaction?
What is a chemical reaction that loses heat to its surroundings
200
Find ΔHrxn for the following reaction: N2 + 2 O2 → 2 NO2 Based on the following data. 2 NO → N2 + O2 ΔH = –180 kJ 2 NO + O2 → 2 NO2 ΔH = –112 kJ
What is 68 kJ
300
Define Specific Heat
What is the amount of heat required to raise the temperature of 1 gram of a substance 1 degree Celsius
300
Equation for heat (q) of a OSU calorimeter
What is q = mass * SH * delta T
300
The sum of the kinetic and potential energies of all of the parties that compose the system [delta] E
What is internal energy
300
What is an endothermic reaction?
What is a chemical reaction that absorbs heat from its surroundings
300
Find the standard enthalpy of formation: CH4(g) + 2 O2(g) ---> CO2(g) + 2 H2O(l) CH4 (g): -74 kJ CO2 (g): -393.5 kJ H2O (l): -285.8 kJ
What is -891.1 kJ
400
The change in enthalpy when one mole of the compound forms from its constituent elements in their standard states
What is standard enthalpy of formation
400
When is [delta]H equal to [delta]E?
What is when any reaction that occurs does NOT involve gasses
400
Energy associated with a reaction at constant volume and energy associated with a reaction at constant pressure
What is internal energy, [delta]E and what is enthalpy, [delta]H
400
What are the signs of [delta H] of an exothermic reaction and an endothermic reaction?
What is negative for exothermic and positive for endothermic
400
100.0 g of nickel at 150 degrees C was placed in 1.00 L of water at 25 degrees Celsius. The final temperature of the water was 26.3 degrees Celsius. What is the specific heat of nickel?
What is 0.44 J/g*C
500
If a chemical equation can be expressed as the sum of series of steps, then [delta]H (rxn) for the overall equation is the sum of the heats of the reactions for each step
What is Hess' Law
500
When is [delta]E different from [delta]H?
What is when a gas is involved
500
Energy associated with a reaction at constant pressure
What is enthalpy, delta H
500
Difference between system and surrounding
What is the portion of the universe we single out for study and which has a boundary vs everything else in the universe
500
Calculate ∆H for the reaction 4 NH3 (g) + 5 O2 (g) → 4 NO (g) + 6 H2O (g) N2 (g) +O2 (g) →2NO(g) ∆H = ‐180.5 kJ N2 (g) +3H2 (g) →2NH3 (g) ∆H = ‐91.8 kJ 2H2 (g) +O2 (g) →2H2O(g) ∆H = ‐483.6 kJ
What is -1628.2 kJ
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