Gen Chem/Spectra
The name of the following compound: PF5
What is Phosphorus Pentafluoride?
A chiral mixture in solution that exhibits a specific rotation of 0
What is a racemic mixture?
This amino acid has restricted motion around its phi bond
What is Proline?
This orbital begins to fill after the 6s orbital
What is the 4f orbital?
The oxidation number of iron in the complex [Fe(CN)6]-3
What is +3
An alcohol group would appear at this wavenumber on an IR spectrum
~3600 cm-1
These reagents are needed for the anti-Markovnikov addition of bromine to an alkene
What are HBR, ROOR (peroxide), and heat/light
This is the most commonly formed conformation of DNA-DNA double helices
What is B DNA?
The equation “ΔG = ΔH - TΔS” only applies to this kind of process
What is isothermal?
Dr. Kazmier's favorite holiday is this
What is Halloween?
The approximate ppm shift of a methoxy group for 1H NMR
What is 4?
DIBALH will reduce an acid chloride to this kind of compound
What is an acid chloride?
This Michaelis-Menten parameter predicts the amount of ligand bound to an enzyme at a specific substrate concentration
What is the KM of the Michaelis constant?
Detergents like SDS form these spherical structures when in hydrophilic solutions
What are micelles?
Peaks present in IR and Raman spectroscopy are caused by these
What are active vibrational nodes?
This gas law describes the inverse relationship between pressure and volume, assuming constant temperature.
What is Boyle's Law?
This German chemist is credited with the discovery of the structure of benzene
Who is August Kekulé?
The first name of one of the famous kinetics duo Michaelis and Menten
Who was Leonor? or Who was Maud?
The reason we cannot analytically solve the Schrödinger equation for the helium atom
The Three-Body Problem
This faculty member is Judy Garland's third cousin
Who is Dr. Meyet
In the equation E=h𝜈, h stands for this constant
What is Planck's Constant? (6.262*10-34 J*s)
This reaction uses an unsaturated halide and a palladium catalyst in base to turn a terminal alkene into an internal alkene through the addition of the R group of the halide
What is the Heck Reaction?
The catalytic triad of a Serine Protease
What is His-Asp-Ser? (Histadine-Aspartate-Serine)
This can be determined using the Debye-Hückel equation
What is the activity of a solution?
If the field splitting energy of a complex is sufficiently small, its valence electrons may end up in this state
What is high spin state?