REDOX
Electrochemical Cells
Ion Flow
Nernst & Thermodynamics
Electroplating
100

This process involves the loss of electrons.

Oxidation

100

This type of cell produces electrical energy spontaneously.

Galvanic (Voltaic) Cell

100

The purpose of the salt bridge is to maintain this property of the solutions.

Electrical Neutrality

100

This equation relates free energy and cell potential.

ΔG=−nFE

100

In electroplating, the object being coated acts as this electrode.

Cathode

200

This electrode is where reduction occurs.

Cathode

200

This type of cell requires an external power source

Electrolytic Cell

200

In a Zn-Cu galvanic cell, electrons flow from this electrode to the copper electrode.

Zinc electrode
200

At equilibrium, this quantity equals zero in a galvanic cell.

Ecell

200

During silver electroplating, silver ions undergo this process at the SPOON.

Reduction

300

These particles travel through the external wire in an electrochemical cell

Electrons

300

A galvanic cell has this sign for ΔG.

Negative

300

In a Zn-Cu galvanic cell, nitrate ions move toward this half-cell

Anode

300

When Q increases, this happens to Ecell.

Decrease
300

This happens to the mass of the silver anode during electroplating.

Decrease

400

In an electrolytic cell, this electrode is connected to the positive terminal of the battery

Anode

400

This is the sign of Ecell∘ in a nonspontaneous reaction.

Negative

400

These ions move toward the cathode compartment through the salt bridge.

Cations

400

The x-intercept of a graph of Ecell vs log⁡(Q) corresponds to this quantity.

log(K)

400

As electroplating continues, the external voltage required generally does this.

Increase

500

This quantity becomes more positive when an atom loses electrons

Oxidation Number

500

In BOTH galvanic and electrolytic cells, this process always occurs at the anode

Oxidation

500

As oxidation occurs at the anode, the solution becomes increasingly ___ without salt bridge ions.

postive

500

A reaction with a very large K value has this sign for Ecell∘.

Postive
500

This explains why increasing concentration differences make electroplating less favorable over time.

Nernst Equation