True or False: K can be either a positive or a negative value.
False!
K can only be positive.
If K > 1, are products or reactants "favored"?
Products!
Which row's values are always positive?
Initial! (I Row)
Find K: A ⇌ B
[A] = 0.50 M [B] = 0.50 M
K = 1!
What is the quadratic formula?
(Do you know the calculator shortcut??)
x = (-b ± √(b² - 4ac)) / (2a)
Calculator shortcut: APPS -> 9: PlySmlt2 -> 1: Polynomial Root Finder. (Order: 2, Real, Dec, Float, Degree.) -> Next -> Solve!
True or False: When equilibrium has been reached, the reaction has stopped.
False!
Concentrations stop changing.
K<1!
What row determines where equilibrium goes?
Find K for the reaction: A + B ⇌ C
[A] = 0.20
[B] = 0.50
[C] = 0.80
K = 8.0
Use the quadratic formula to solve for x:
3x2 − 5x − 2 = 0
x = 2 or x = -0.3
True or False: Reactions can reach equilibrium from any starting conditions.
True!
What would the expression for the equilibrium constant be?
2A + B ⇌ 3C + D2
K= [C]3[D2] / [A]2[B]
Which direction would equilibrium go based on this ice table?
A + B ⇌ C
I. 1.0 1.0 0
C. -x -x +x
E 1.0-x 1.0-x x
Equilibrium went right! (Products had a +x)
Find K: 2A ⇌ 3B
[A] = 0.40
[B] = 0.80
K = 3.2!
Use the quadratic formula to solve for x:
2x2 − 7x + 3 = 0
x = 3 or x = 0.5
True or False: Stochiometric coefficients show up in the C row only.
True!
If K is 4.53 x 10-4, are products or reactants "favored"?
Reactants!
K<1
Create an ICE table: A ⇌ B
Initial concentrations: It is okay for x to be unknown here
[A] = 1.0 M
[B] = 0 M
A ⇌ B
I 1.0 0
C -x +x
E 1.0 - x x
Find K: 2A ⇌ B
[A] = 0.50
[B] = 0.50
K = 2.0!
2A⇌B K=8.0
Initial concentrations: [A]=1.00 M [B]=0
After solving the equilibrium expression, you obtain:
x=0.80 and x=0.50. Which x is correct?
x = 0.50
True or False: The change in concentration for H2O (l) can be shown in an ICE table.
False!
ICE tables never include solids or liquids.
What's the difference between where equilibrium lies and where equilibrium goes?
K tells you where equilibrium LIES. (K>1, K<1, K=1)
C row tells you where equilibrium GOES. The signs tell you the direction the reaction shifts.
Create an ICE table: N₂O₄ ⇌ 2NO₂
Initial: It is okay for x to be unknown here
[N₂O₄] = 0.574
[NO₂] = 0
N₂O₄ ⇌ 2NO₂
I 0.574 0
C -x +2x
E 0.574 - x 2x
2A ⇌ B
K = 4.0
At equilibrium: [A] = 0.50. Find [B]
B = 1.0 M!
Find x: N2O4 ⇌ 2NO2
Initial Concentrations: [N2O4] = 0.574. [2NO2] = 0
K = 4.65 x 10-3