what is the difference between electron geometry and molecular geometry?
Electron geometry describes the arrangement of all electron pairs (both bonding and lone pairs) around a central atom, while molecular geometry describes the arrangement of only the bonded atoms around the central atom
what does the valence bond theory say
that atoms share electrons when atomic orbitals overlap
balance:
C2H4O2 + PCl3 = C2H3OCl + H3PO3
3C2H4O2 + PCl3 = 3C2H3OCl + H3PO3
what is a percipitate?
an insoluble product that forms from a solution
what is a redox reaction?
A redox reaction is the sum of an oxidation half-reaction and a reduction half-reaction.
Basically one atom loses and electron (oxidizes) and another atom gains an electron (reduces)
What is the bond angle in ClO4-?
109
what are intermolecular formulas?
they are the attractive forces between molecules
balance:
Fe + H2O = Fe3O4 + H2
3Fe + 4H2O = Fe3O4 + 4H2
what is the difference between the solute and the solvent?
the solute is the thing that is being dissolved and the solvent (present in the largest amounts) is doing the dissolving
what are the oxidation numbers of ClO3-?
Cl- +5
O- -2 (x3)
Predict the shape of SeH4
see-saw
define hydrogen bonding
A special type of dipole-dipole interaction that occurs when a hydrogen atom is bonded to a highly electronegative atom (N, O, or F)
Consider the following reaction:
Al + HBr → AlBr3 + H3
When 3.22 moles of Al react with 4.96 moles of HBr, how many moles of H2 are formed?
2.15 moles
Bronsted acid v. Bronsted base
Bronsted acid- proton donor
Bronsted base- proton acceptor
25.0 mL of a 0.2450 M NH4Cl solution is added to 55.5 mL of 0.1655 M FeCl3 . What is the concentration of chloride ion in the final solution?
0.418 M
predict the shape of sulfate
tetrahedral
How many sigma and how many pi bonds are present in hexane?
19 sigma
Write the balanced equation for the reaction given below:
CuCl2 + NaNO3 Cu(NO3)2 + NaCl
If 15 grams of copper (II) chloride react with 20. grams of sodium nitrate, how much sodium chloride can be formed?
13.03 grams
Write the molecular, ionic, and net ionic equations for the reaction that occurs when aqueous solutions of lead acetate [Pb(C2H3O2)2] and calcium chloride
(CaCl2), are combined
Molecular:
Pb(C2H3O2)2(aq) + (CaCl2)(aq)=
PbCl2(s)+ Ca(C2H3O2)2 (aq)
Ionic:
Pb2+ (aq) + 2C2H3O2-(aq)+Ca2+(aq)+Cl2-(aq) = PbCl2(s) + Ca2+(aq) + 2C2H3O2-(aq)
Net Ionic:
Pb2+ (aq) + Cl2-(aq) = PbCl2(s)
What mass of Li3PO4 is needed to prepare 1000.0 mL of a solution having a lithium ion concentration of 0.247 M?
28.6 g
if a molecule has 6 domains, what is the electron geometry, hybridization, and bond angles?
octahedral, sp3d3, 90
what is orbital hybridization?
A concept in valence bond theory that explains the observed shapes of molecules. It involves the mixing of atomic orbitals within an atom to create hybrid
orbitals that have different shapes and energies than the original atomic orbitals
Starting with a 2.0 M stock solution of hydrochloric acid, four standard solutions (1 to 4) are prepared by sequential diluting 10.00 mL of each solution to 250.00 mL. Determine (a) the concentrations of all four standard solutions and (b) the number of moles of HCl in each solution.
D1: 8.00 x 10-2M , 2.00 x 10-2mol
D2: 3.20 x 10-3M, 8.00 x 10-4mol
D3: 1.28 x 10-4M, 3.20 x 10-5mol
D4: 5.12 x 10-6M, 1.28 x 10-6mol