Which statement describes the trend in atomic radius across Period 3?
Increases
Decreases
Remains the same
Increases then decreases
2. Decreases
Atomic radius decreases across Period 3 due to increasing nuclear charge, pulling electrons closer.
Which element in Period 3 has the smallest atomic radius?
Sodium
Magnesium
Silicon
Argon
4. Argon
Argon has the smallest atomic radius due to its high nuclear charge and no additional electron shells.
Which element in Period 3 has the highest melting point?
Silicon
Sodium
Sulfur
Aluminium
Correct Answer: 1. Silicon
Silicons covalent network structure requires significant energy to break.
What type of bonding is present in SiO2?
Ionic
Simple molecular
Giant covalent
Metallic
Correct Answer: 3. Giant covalent
SiO2 forms a giant covalent lattice with strong Si-O bonds.
Which Period 3 element forms an oxide that is amphoteric?
Sodium
Magnesium
Aluminium
Silicon
Correct Answer: 3. Aluminium
Al2O3 reacts with both acids and bases, showing amphoteric behavior.
Which Period 3 oxide reacts with water to give a solution with pH
~13?
SiO2
P4O10
Na2O
SO2
Correct Answer: c) Na2O
Na2O + H2O 2NaOH, a strong base, yielding pH ~13.
What causes the decrease in atomic radius across Period 3?
Increased shielding
Decreased nuclear charge
Increased nuclear charge
Increased electron-electron repulsion
Correct Answer: c) Increased nuclear charge
More protons increase nuclear attraction, reducing atomic radius.
Which chloride hydrolyses completely in water to give a strongly acidic solution?
NaCl
MgCl2
SiCl4
AlCl3
Correct Answer: c) SiCl4
SiCl4 + 4H2O --> Si(OH)4 + 4HCl, producing a strongly acidic solution.
What is the oxidation state of sulfur in SO2?
1. +2
2. +4
3. +6
4. 0
Correct Answer: b) +4
Oxygen is -2; sulfur is +4 to balance SO2.
Which statement is true about electrical conductivity across Period 3?
Increases across the period
Decreases uniformly
Increases then decreases
Remains constan
Correct Answer: c) Increases then decreases
Conductivity peaks at aluminum due to metallic bonding, then drops for non-metals.
The reaction of NaCl with water produces a solution with pH:
Acidic
Neutral
Strongly acidic
Basic
Correct Answer: b) Neutral
NaCl dissolves to form Na+ and Cl–, which do not affect pH.
The oxidation state of phosphorus in PCl5 is:
a) +3
b) +5
0
-3
Correct Answer: b) +5
Chlorine is -1; phosphorus is +5 to balance PCl5.
Which element in Period 3 forms a chloride that fumes in moist air due to hydrolysis?
Na
Mg
Al
Ar
Correct Answer: c) Al
AlCl3 hydrolyzes to produce HCl fumes:
AlCl3 + 3H2O --> Al(OH)3 + 3HCl.
What is the pH of the solution formed when SO2 dissolves in water?
Around 1
Around 3
Around 7
Around 10
Correct Answer: b) Around 3
SO2 + H2O --> H2SO3, a weak acid, yields pH ~3.
The oxide formed when phosphorus reacts with oxygen is:
P4O6
P4O10
PO
P2O5
Correct Answer: b) P4O10
Phosphorus forms P4 + 5O2--> P4O10
Which Period 3 chloride has a simple molecular structure?
NaCl
AlCl3
MgCl2
Non
Correct Answer: b) AlCl3
AlCl3 forms a dimeric Al2Cl6 with a simple molecular structure in vapor.
Which Period 3 element does not form a stable chloride?
Phosphorus
Silicon
Sulfur
Aluminium
Correct Answer: c) Sulfur
Sulfur does not form a stable chloride due to its bonding preferences.
Which element in Period 3 has the highest first ionisation energy?
Na
Mg
Cl
Ar
Correct Answer: d) Ar
Argons full valence shell results in the highest ionisation energy.
The melting point of phosphorus is lower than silicon because:
Phosphorus has simple molecular structure
Phosphorus is more reactive
Silicon has a lower atomic radius
Phosphorus has giant covalent structure
Correct Answer: a) Phosphorus has simple molecular structure
Phosphorus (P4) has weak intermolecular forces, unlike silicons covalent network.
Which oxide of Period 3 behaves as a base with acids?
SO2
SO3
MgO
P4O10
Correct Answer: c) MgO
MgO reacts with acids to form salts, acting as a base.
The chloride of which element sublimes easily and hydrolyses in water?
NaCl
AlCl3
MgCl2
None
Correct Answer: b) AlCl3
AlCl3 sublimes and hydrolyzes to form HCl and Al(OH)3.
The melting point of sulfur is low because it has:
Ionic bonds
Giant covalent structure
Simple molecular structure
Metallic bonding
Correct Answer: c) Simple molecular structure
Sulfur (S8) has weak van der Waals forces, lowering its melting point
Which statement is true for Na and Mg reacting with water?
Both react violently
Only Na reacts
Only Mg reacts
Neither reacts
Correct Answer: b) Only Na reacts
Sodium reacts vigorously; magnesium reacts very slowly with water.
The pH of the solution formed when P4O10 reacts with water is:
Around 14
Around 7
Around 1
Around 9
Correct Answer: c) Around 1
P4O10 + 6H2O --> 4H3PO4, a strong acid, yields pH ~1.
Which Period 3 oxide does not dissolve in water but reacts with acids and bases?
SiO2
P4O10
SO2
Na2O
Correct Answer: a) SiO2
SiO2 is insoluble but reacts with strong bases and acids like HF.