The equation H2(g) + I2(g) --> 2HI(g) is a(n)
Overall Reaction
In a single step reaction represented by the equation A + B --> C, the rate law for the forward one-step reaction is:
R=K[A][B]
forward reaction rate equals reverse reaction rate
Equilibrium
If the pressure on the equilibrium system is increased
2CO(g) + O2(g) --> 2CO2(g)
then:
equilibrium will shift to the right to make more CO2
DE is -ve
Exothermic reaction
Sequence of steps in a reaction
Reaction Mechanism
process used to speed up chemical reactions
Catalysis
value of equilibrium constant changes with
Temperature
Decreasing temperature will lead to:
a. increases the reaction rate
b. decreases the reaction rate
c. might increase or decrease the reaction rate d. doesn’t affect the reaction rate
b. decrease the reaction rate
chemical equilibrium expression for the equation
2A2B + 3CD --> A4D + C3B2
Keq = [A4D][C3B2] / [A2B]2[CD]3
Minimum energy required for an effective collision
Activation Energy
the slowest step in a reaction
Rate-determining step
If K is more than 1 which substances are favored, Products or reactants?
Products
Adding a catalyst will:
a. increases the reaction rate
b. decreases the reaction rate
c. might increase or decrease the reaction rate
d. doesn’t affect the reaction rate
a. increases the reaction rate
The activation energy for a reaction is the energy difference between the
reactant and activated complex
short-lived transitional structure formed during a collision
Activated-Complex
It provides an alternative pathway with a lower activation energy
Catalyst
Increasing surface are will:
a. increases the reaction rate
b. decreases the reaction rate
c. might increase or decrease the reaction rate
d. doesn’t affect the reaction rate
a. increases the reaction rate
Consider the reaction represented by the equation Ag2SO4(aq) ⇌ 2Ag+(aq) + SO42-(aq).
You can shift the equilibrium to favor the reverse reaction by adding
common ion
When sodium acetate, NaCH3COO, is added to the following system
CH3COOH(aq) + H2O(l) ⇌ CH3COO-(aq) + H3O+(aq)
What will increase and what will decrease
[H3O+] decreases [CH3COOH] increases
In an energy profile the activated complex is found at the
Peak of the curve
A reaction is zero order in reactant A and first order in reactant B. What happens to the reaction rate when the concentrations of both reactants are doubled?
the reaction rate is doubled
An equilibrium mixture of SO2, O2, and SO3 gases at 1500 K is determined to consist of 0.344 mol/L SO2, 0.172 mol/L O2, and 0.56 mol/L SO3. What is the equilibrium constant for the system at this temperature? The balanced equation for this reaction is:
2SO2(g) + O2(g) --> 2SO3(g)
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Adding a charged particle common to two solutes decreases solute concentration is known as
Common ion effect
Reactions run to completion due to
- formation of a gas
- formation of a precipitate
- formation of slightly ionized product