Amines
Aldehydes
Ketones
Carboxylic Acid
and their Derivatives
100
Amines with the general formula NHR2.
What is secondary amine? section 19-2
100
As an aldehyde my value appears between 9-10 ppm on this spectra.
What is H1 NMR? Section 18.5
100
A condition requirement when using such nucleophiles such as water in a nucleophilic addition.
What is an acidic condition? Section18-12 pg 834
100
The reserved name for a carbon two carbons removed from a carboxylic acid.
What is beta carbon? Section 20-2
100
The least reactive derivative.
What is amide (ppt) or carboxylate (book). Section 21-5
200
The common classification for an amine in organic chemistry. I.E. amine always behave as _______ in organic.
What is base(s)? Section 19-5
200
Using a primary alcohol and this oxidizing reagent you can stop at the formation of an aldehyde?
What is PCC or PCD? Section 18.7 pg 821
200
I am a product of the reaction between a ylide and a ketone.
What is an alkene? Section 18-13 Wittig.
200
Is the type of reagent required for the transformation of a carboxylic acid to a carboxylate (acid salt).
What is a strong base? Section 20-5
200
Is the product formed when an anhydride reacts with an alcohol.
What is an ester? Section 21-5 pg 1001
300
As an amine I often produce this type of parent ion in mass spectrometry.
What is odd numbered? Section 19-9
300
An aldehyde is generated by the use of this starting material followed by reacting with Sia2BH followed by peroxide and base.
What is an alkyne? Section 18-11 review in section 9-9.
300
It is the product of ammonia and a ketone in a condensation reaction.
What is an imine? Section 18-17
300
Requires heat and this reagent to convert a benzylic carbon to a carboxylic acid.
What is Chromate oxidant (Aqueous oxidant)? Section 20-8
300
The product formed when an amine and a ester react.
What is an amide? Section 21-13
400
This type of elimination allow me an amine to act as a leaving group.
What is Hofmann (elimination)? Section 19-15
400
The most common type of reaction that occurs with aldehydes as the starting material. (Think general!)
What is nucleophilic addition? Section 18-12
400
One of two effects responsible for the stabilization of intermediates in ketone reaction.
What is induction or resonance? Section 18-12
400
I am required to convert carboxylic acids to acyl chlorides.
What is thionyl chloride? Section 20-15
400
The functional group that has the same oxidation state as other derivatives but doesn't contain a carbonyl carbon.
What is the nitrile? Section 21-13
500
The production of this product occurs with treatment of a primary alkylamine with sodium nitrite and hydrochloric acid.
What is a diazonium salt? Section 19-18
500
This product is produced upon protection of an aldehyde.
What is an acetal? Section 18-18
500
The name given to the substituent form of a ketone.
What is -oxo? Section 18-3
500
A reaction that leads to the production of alcohols from carboxylic acids.
What is reduction?
500
The reagent needed to avoid competition of the nucleophile during derivative interconversion.
What is pyridine? pg 1019,