Trivia
Titrations
Proteins/Amino Acids
Galvanic/Electrolytic
Equilibrium
100

What is the official capital of Sri Lanka?

Sri Jayawardenapura Kotte

100

List 2 Characteristics of a substance that something need to be a primary standard

  • high molecular weight 
  • not deliquescent / hygroscopic 
  • soluble in water 
  • obtainable in pure form
100

The secondary structures of proteins are stabilized by this intermolecular force.

What is Hydrogen Bonds

100

Which one of the following statements BEST describes the function of an anode in an electrolytic cell?

(a)          The anode is the electrode at which reduction occurs.

(b)          The anode is the only electrode at which OH¯ (aq) ions are produced.

(c)           The anode is the electrode which attracts positive ions.

(d)          The anode is the electrode that is oxidised.

(d) The anode is the electrode that is oxidised.

100

Consider the following equilibrium system, which is formed when solid white phosphorus reacts with fluorine gas to form phosphorus trifluoride vapour.

P4(s)   +   6 F2(g)   ⇌   4 PF3(g)

What is the correct equilibrium constant (K) expression for the following reaction?

Ans: K=[PF3]^4/[F2]^6

200

How old is Ms. Pinya in 2023?

48

200

What is the average amount of titre:
Sample 1: 24.65

Sample 2: 24.86

Sample 3: 25.05

Sample 4: 24.92

29.94

200

This amino acid can produce the strongest bonds

What is Cysteine

200

Which of the following statements regarding fuel cells is correct?

(a)          Fuel cells are a type of galvanic cell.

(b)          Fuel cells are a type of electrolytic cell.

(c)           Fuel cells are a type of primary cell.

(d)          Fuel cells are a type of secondary cell.

(a) Fuel cells are a type of galvanic cell.

200

Bromine water, which is a dilute aqueous solution of bromine in water, is slightly acidic because of its reaction with water, represented by the following equation:

  Br2 (aq)   +   H2O (l)              ⇌      HBrO (aq)    +    H+ (aq)    +    Br – (aq)               

In aqueous solution, bromine, Br2 (aq) is brown. Hypobromous acid, HBrO (aq), and bromide ions, Br – (aq) are both colourless.

State and explain the colour changes that would be observed, if the following changes are made to the system at equilibrium.

(a)       Addition of NaOH (aq).                                                                                   (3 marks)

Colour: Brown colour fades, or solution turns less brown.

Explanation: Addition of OH- causes a decrease in the [H+] as the combination of the two ions produce water (H2O). This will result in the rate of collision of reactants being greater than that of products, shifting the equilibrium to the right, favouring the forward reaction rate. Thus the [Br2] decreases causing the brown colour to fade. 

300

Who is the best teacher?

Brendan

300

What is the pH solution given that [H+] = 0.1967

0.706

300

When an amino acid is in an low pH, this occurs

What is gaining a hydrogen atom

300

When the reactant for a half cell is a gas, what type of electrode do you use? Why do you use this type of electrode?

An inert electrode, such as platinum or graphite, is used when the reactant is a gas. This is because there is no solid conductor for the gas to conduct electrons through the wire.

300

In the following equilibrium system, nitrogen, oxygen and chlorine gases combine to produce nitrosyl chloride vapour. This equilibrium system can form at temperatures of around 400 °C.


N2(g)      +      O2(g)      +      Cl2(g)      ⇌      2 NOCl(g)

 colourless       colourless      greenish-yellow       yellow 


If an equal number of moles of N2(g), O2(g) and Cl2(g) were injected into a sealed flask at 400 °C;

Explain what would happen to the forward and reverse reaction rates as the system moved to establish equilibrium.

  • the forward reaction rate would initially be high, as the molecules collide to produce NOCl, and would slowly decrease as the reactants form products 
  • the reverse reaction rate would initially be zero, but as NOCl is produced it would begin to increase 
  • at equilibrium the rate of forward and reverse reactions becomes equal 
400

Which country bears the highest mountain of the world?

Nepal

400

Potassium hydrogen iodate, KH(IO3)2, is a common primary standard used in acid-base titrations.

A sample of KH(IO­3­)­2­(s) weighing 1.218 g was dissolved in distilled water and made up to 250.0 mL in a volumetric flask. 20.00 mL aliquots of this primary standard were taken and titrated against a sodium hydroxide solution, NaOH(aq), of unknown concentration. An average titre of 23.74 mL was required to reach the end point.

The equation for the titration reaction is;

KH(IO3)2(aq)  +  NaOH(aq)  ®  NaIO3(aq)  +  KIO3(aq)  +  H2O(l)

Q:Calculate the concentration of the NaOH(aq) solution. State your answer to the appropriate number of significant figures.

0.01053M

400

What are the most prevalent bonds within protein structures

What is Hydrogen, Peptide and Disulphur bonds

400

Why do lithium-ion batteries get lighter as they lose charge, and heavier when on full charge?

As the reaction takes place, hydrogen gas is produced. Since hydrogen gas is lighter then air, is experiences a buoyant force and thus appears lighter

400

Aluminium salts are acidic due to the presence of the hexaaqualuminate ion, [Al(H2O)6]3+ which is formed when a soluble aluminium salt is dissolved in water. This ion undergoes hydrolysis as follows:

[Al(H2O)6]3+ (aq)   +   H2O (l)       ⇌      [Al(OH)(H2O)5]2+ (aq)   +   H3O+ (aq)

A solution of aluminium nitrate has a pH of 5.6.

It was found that when the aluminium nitrate solution was warmed, the pH of the solution decreased. From this information, deduce whether the forward reaction in the above equilibrium is endothermic or exothermic. Explain your reasoning:

As the pH has decreased due to an increase in the [H+], caused by an increase in temp;   (1)  clearly the Forward reaction has been favoured by this imposed change, (ie. higher temp). 

In order for the reaction to respond in this way, (ie. shifting the equilibrium to the right), 

the Forward reaction must be ENDOTHERMIC

500

What year did Ms. Pinya migrate to Australia?

2005

500
  1. Ellagic acid is found in fruits and vegetables such as raspberries, strawberries, walnuts and pomegranates. It has been shown to have antioxidant and anticancer properties and has been studied for its potential use as a treatment for viral and bacterial infections, inflammation, some chronic diseases and as a skin anti-ageing agent

53.70 g of raspberries were liquefied by pulverising and dissolving in an appropriate solvent. The liquid raspberry mixture was made up to 100.0 mL in a volumetric flask. 20.00 mL aliquots were then taken and titrated against a standard 3.802 x 10-3 mol L-1 NaOH solution. The titration equation is given below.

C14H6O8(aq)  +  4 NaOH(aq)  -->  4 H2O(l)  +  Na4C14H2O8(aq)

If the concentration of ellagic acid is known to be 40.06 mg per 100.0 g of raspberries;

 Determine the theoretical value of the average titre that the professor should obtain. (Assume all sources of error were minimised and ellagic acid is the only compound in the raspberries that reacts in the titration).

14.98 mL

500

When a protein becomes denatured, this is the cause for its loss of shape

(What is weaking or loss of hydrogen bonds)

500

The electroplating of various metals plays an extremely important role in industry. These reactions can be carried out on a small scale in the laboratory using standard laboratory equipment.

A typical spoon can be chrome electroplated utilising a chromium electrode and an acidified aqueous chromium nitrate solution. Using a labelled diagram, explain the process involved in electroplating the spoon.

Your answer should pay particular attention to the following areas:

 (a)         How the cell can be constructed. (A diagram with clear labels for the anode, cathode, electrolyte, direction of flow of electrons and ions).

[on my computer, can show you for answer. Person needs to draw diagram on board]

500

Nitric oxide is an unstable molecule, and when it comes into contact with ozone the following reaction takes place, producing nitrogen dioxide (NO2) and oxygen (O2).

  O3(g)  +  NO(g)  ⇌  NO2(g)  +  O2(g) 

 The activation energy for the forward reaction is 10.8 kJ, whilst the activation energy for the reverse reaction is 210.5 kJ.

Considering the activation energy values provided;

Comment on the likely reversibility of this reaction and explain how this would affect the size of the equilibrium constant (Kc):

  • not likely to be reversible, since forward Ea very small and reverse Ea very large 
  • this suggests there would be lots of products present at equilibrium 
  • this would result in a large value of Kc