Colligative properties
Equilibrium
Thermodynamics
Kinetics
Electrochemistry
100

Which solution has the highest freezing point: 0.1 m NaCl, 0.1 M CaCl₂, or 0.1 M glucose?

NaCl

100

For an exothermic reaction, how does increasing the temperature affect the equilibrium?

Their concentrations don’t change during the reaction; they are considered constant.

100

100: What is the sign of ΔS when a solid dissolves in water?




Positive — increased disorder.

100

What plot gives a straight line for a first-order reaction?

ln[A] vs. time

200

Explain why an exothermic reaction can be non-spontaneous.




If ΔS is very negative and T is high, ΔG can still be positive.

200

If the E°cell for a reaction is negative, what can you say about the spontaneity?

The reaction is non-spontaneous under standard conditions.

300

What is osmotic pressure, and how does it relate to colligative properties?

Osmotic pressure is the pressure needed to stop solvent flow through a semipermeable membrane. It increases with the number of solute particles — a colligative property.

 

300

What happens to the solubility of AgCl when NaCl is added to the solution?

Solubility decreases due to the common ion effect (Cl⁻ is added, shifting equilibrium left).

300

What is the change in entropy of the system when 1 mol of ice melts melts at 0°C (273 K)? 

Give your answer in J/mol*K

22.0 J/mol*K

300

What even are standard reduction potentials? 

The Voltage generated (or required) to pass electrons from a hydrogen gas electrode to the electrode on the table. They are considering cells containing 1 M of ion solution at 1 atm. 

This gives you a standard to see which way electrons will flow when any two electrodes are connected.

400

Will a precipitate form if [Ba²⁺] = 1.0 × 10⁻³ M and [SO₄²⁻] = 1.0 × 10⁻⁴ M? (Ksp of BaSO₄ = 1.1 × 10⁻¹⁰)




Q = (1.0 × 10⁻³)(1.0 × 10⁻⁴) = 1.0 × 10⁻⁷ > Ksp ⇒ Yes, a precipitate forms

400

How many grams of copper are plated out when 2.00 A of current is passed for 1.50 hours through a Cu²⁺ solution?
(Molar mass of Cu = 63.5 g/mol, 1 Faraday = 96,485 C/mol e⁻)

1 Faraday is the charge carried in one mol of electrons

3.55g


500

Balance the following redox reaction in basic solution: 
What is the sum of all the coefficients in the solution. 



ANSWER: 16

700

The rate constant doubles when temperature increases from 298 K to 308 K. 

If the reaction is 0 order, how much time in seconds does it take to go from 0.46 M of reactant to 0.1M when the frequency factor is 2 at this new temperature.  



700

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